Information on EC 2.4.1.199 - beta-mannosylphosphodecaprenol-mannooligosaccharide 6-mannosyltransferase
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The expected taxonomic range for this enzyme is: Mycolicibacterium smegmatis
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beta-mannosylphosphodecaprenol-mannooligosaccharide 6-mannosyltransferase
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beta-D-mannosylphosphodecaprenol + (1->6)-alpha-D-mannosyloligosaccharide = decaprenol phosphate + (1->6)-alpha-D-mannosyl-(1->6)-alpha-D-mannosyl-oligosaccharide
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hexosyl group transfer
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beta-D-mannosylphosphodecaprenol:(1->6)-alpha-D-mannosyloligosaccharide 6-alpha-D-mannosyltransferase
Involved in the formation of mannooligosaccharides in the membrane of Mycobacterium smegmatis.
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mannosylphospholipid-methylmannoside alpha-1,6-mannosyltransferase
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mannosyltransferase, mannosylphospholipid-methylmannoside alpha-1,6-
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brenda
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mannosylphosphodecaprenol + 1,6-alpha-D-mannooligosaccharides
decaprenol phosphate + 1,6-alpha-D-mannosyl-1,6-alpha-D-mannooligosaccharides
mannosylphosphodecaprenol + 1,6-alpha-D-mannopentaose
decaprenol phosphate + 1,6-alpha-D-mannohexaose
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mannosylphosphodecaprenol + 1,6-alpha-D-mannotetraose
decaprenol phosphate + 1,6-alpha-D-mannosylpentaose
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mannosylphosphodecaprenol + 1,6-alpha-D-mannotriose
decaprenol phosphate + 1,6-alpha-D-mannosyltetraose
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mannosylphosphodecaprenol + methyl-alpha-D-mannoside
decaprenol phosphate + ?
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mannosylphosphodecaprenol + myo-inositol-trimannoside
decaprenol phosphate + ?
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with an 1,6-alpha-mannobiose unit as part of its structure
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additional information
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substrate specificity
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mannosylphosphodecaprenol + 1,6-alpha-D-mannooligosaccharides

decaprenol phosphate + 1,6-alpha-D-mannosyl-1,6-alpha-D-mannooligosaccharides
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poor substrates are mannose and 1,6-alpha-mannobiose, no substrates are 1,2-, 1,3-alpha-mannooligosaccharides or myo-inositol-2,6-dimannoside
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mannosylphosphodecaprenol + 1,6-alpha-D-mannooligosaccharides
decaprenol phosphate + 1,6-alpha-D-mannosyl-1,6-alpha-D-mannooligosaccharides
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involved in the formation of mannooligosaccharides in membrane of Mycobacterium smegmatis
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mannosylphosphodecaprenol + 1,6-alpha-D-mannooligosaccharides
decaprenol phosphate + 1,6-alpha-D-mannosyl-1,6-alpha-D-mannooligosaccharides
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involved in the formation of mannooligosaccharides in membrane of Mycobacterium smegmatis
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2.6
1,6-alpha-D-mannopentaose
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2.4
1,6-alpha-D-mannotetraose
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2
1,6-alpha-D-mannotriose
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35.7
1,6-alpha-mannobiose
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28.6
methyl-alpha-D-mannoside
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additional information
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brenda
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Yokoyama, K.; Ballou, C.E.
Synthesis of alpha 1-6-mannooligosaccharides in Mycobacterium smegmatis. Function of beta-mannosylphosphoryldecaprenol as the mannosyl donor
J. Biol. Chem.
264
21621-21628
1989
Mycobacterium smegmatis
brenda
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