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Information on EC 1.14.14.44 - phenylacetaldehyde oxime monooxygenase

for references in articles please use BRENDA:EC1.14.14.44
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IUBMB Comments
This cytochrome P-450 (heme-thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucosides (R)-prunasin and (R)-amygdalin. It catalyses three different activities - isomerization of the (E) isomer to the (Z) isomer, dehydration, and C-hydroxylation.
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The expected taxonomic range for this enzyme is: Prunus mume
Synonyms
cyp71an24, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = (R)-mandelonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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overall reaction
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(E)-phenylacetaldehyde oxime = (Z)-phenylacetaldehyde oxime
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(1a)
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(Z)-phenylacetaldehyde oxime = phenylacetonitrile + H2O
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(1b)
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phenylacetonitrile + [reduced NADPH-hemoprotein reductase] + O2 = (R)-mandelonitrile + [oxidized NADPH-hemoprotein reductase] + H2O
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(1c)
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