Information on EC 1.14.14.147 - 3-epi-6-deoxocathasterone 23-monooxygenase

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IUBMB Comments
A cytochrome P-450 (heme-thiolate) protein involved in brassinosteroid biosynthesis. C-23 hydroxylation shortcuts bypass campestanol, 6-deoxocathasterone, and 6-deoxoteasterone and lead directly from (22S,24R)-22-hydroxy-5alpha-ergostan-3-one and 3-epi-6-deoxocathasterone to 3-dehydro-6-deoxoteasterone and 6-deoxotyphasterol .
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The enzyme appears in viruses and cellular organisms
Synonyms
CYP90C1, CYP90C1/ROTUNDIFOLIA3, CYP90D1, cytochrome P450 90C1, ROT3, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + [reduced NADPH-hemoprotein reductase] + O2 = 3-dehydro-6-deoxoteasterone + [oxidized NADPH-hemoprotein reductase] + H2O
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(2)
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3-epi-6-deoxocathasterone + [reduced NADPH-hemoprotein reductase] + O2 = 6-deoxotyphasterol + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
(1)
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