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Literature summary for 4.2.3.122 extracted from

  • Croteau, R.; Satterwhite, D.M.
    Biosynthesis of monoterpenes: Stereochemical implications of acyclic and monocyclic olefin formation by (+)- and (-)-pinene cyclases from sage (1989), J. Biol. Chem., 264, 15309-15315.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Salvia officinalis
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
geranyl diphosphate
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Salvia officinalis (+)-alpha-pinene + diphosphate products are (+)-alpha-pinene, (+)-camphene, and lesser amounts of (+)-limonene, myrcene, and terpinolene. The bicyclic products of pinene and camphene are derived via the cyclization of the cisoid, anti-endo-conformers of the bound, tertiary allylic intermediate (3R)-linalyl diphosphate. A preassociation mechanism of geranyl diphosphate is suggested in which optimum folding of the terpenyl chain precedes the initial ionization step ?
linalyl diphosphate
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Salvia officinalis myrcene + diphosphate products are disproportionately high levels of acyclic olefins myrcene and ocimene and monocyclic olefins limonene and terpinolene. Limonene is formed via conformational foldings in addition to the cisoid, anti-endo-pattern ?
neryl diphosphate
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Salvia officinalis myrcene + diphosphate products are disproportionately high levels of acyclic olefins myrcene and ocimene and monocyclic olefins limonene and terpinolene. Limonene is formed via conformational foldings in addition to the cisoid, anti-endo-pattern ?