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4.2.3.92: (+)-gamma-cadinene synthase

This is an abbreviated version!
For detailed information about (+)-gamma-cadinene synthase, go to the full flat file.

Reaction

(2E,6E)-farnesyl diphosphate
=
(+)-gamma-cadinene
+
diphosphate

Synonyms

CDS, TPS

ECTree

     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.92 (+)-gamma-cadinene synthase

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Resultsin table
5AA Sequence
2Cloned(Commentary)
3Organism
1Reaction
3Reference
3Source Tissue
2Substrates and Products (Substrate)
2Synonyms
1Systematic Name

Substrates Products

Substrates Products on EC 4.2.3.92 - (+)-gamma-cadinene synthase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
(+)-gamma-cadinene + diphosphate
show the reaction diagram
-
-
-
-
?
(2E,6E)-farnesyl diphosphate
gamma-cadinene + delta-cadinene + diphosphate
show the reaction diagram
-
the recombinant enzyme catalyzes the formation of three sesquiterpenes from farnesyl diphosphate: delta-cadinene, gamma-cadinene and lower levels of alpha-copaene
gamma-cadinene and delta-cadinene are the main products post harvest and in mature fruit stage, respectively (about 60% yield each)
-
?