4.2.3.139: valerena-4,7(11)-diene synthase

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For detailed information about valerena-4,7(11)-diene synthase, go to the full flat file.

Reaction

Synonyms

sesquiterpene synthase 1, TPS1, VoTPS2

ECTree

     4 Lyases

         4.2 Carbon-oxygen lyases

             4.2.3 Acting on phosphates

                4.2.3.139 valerena-4,7(11)-diene synthase

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Results	in table
2	AA Sequence
1	Cloned(Commentary)
1	KM Value [mM]
2	Organism
1	pH Optimum
1	Reaction
2	Reference
2	Source Tissue
3	Substrates and Products (Substrate)
4	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
1	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 4.2.3.139 - valerena-4,7(11)-diene synthase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

(2E,6E)-farnesyl diphosphate

valerena-4,7(11)-diene + diphosphate

2 entries

additional information

?

-

Valeriana officinalis

L0HP52

poor substrate: geranyl diphosphate

730025

-

-

?

(2E,6E)-farnesyl diphosphate

valerena-4,7(11)-diene + diphosphate

Valeriana officinalis

-

-

719468

-

-

?

(2E,6E)-farnesyl diphosphate

valerena-4,7(11)-diene + diphosphate

Valeriana officinalis

L0HP52

mechanism: C1 forms a bond with C11 of the originating farnesyl diphosphate molecule to form a caryophyllenyl carbocation followed by opening of the cyclobutyl ring to yield the desired isobutenyl side chain

730025

-

-

?