4.2.3.10: (-)-endo-fenchol synthase
This is an abbreviated version!
For detailed information about (-)-endo-fenchol synthase, go to the full flat file.
Reaction
Synonyms
(-)-endo-fenchol cyclase, cyclase, (-)-endo-fenchol, EC 4.6.1.8, FENS, geranyl pyrophosphate:(-)-endo-fenchol cyclase
ECTree
4.2.3.10 (-)-endo-fenchol synthaseAdvanced search results
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results (Substrates Products
Substrates Products on EC 4.2.3.10 - (-)-endo-fenchol synthase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
2,3-cyclopropylgeranyl diphosphate
?
-
at 53% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products
-
-
?
6,7-dihydrogeranyl diphosphate
?
-
at 35% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products
-
-
?
dimethylallyl diphosphate
dimethylallyl alcohol + diphosphate
-
at the same rate as the cyclization of geranyl diphosphate
-
?
farnesyl diphosphate
?
-
at 25% of the rate of conversion of geranyl diphosphate, formation of ether-soluble products
-
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
mechanism of the isomerization-cyclization reaction
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
mechanism of the isomerization-cyclization reaction
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
stereochemistry, syn-isomerization of substrate to (3R)-linalyl diphosphate and cyclization of the latter via the anti-endo-conformer
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
(3R)-linalyl diphosphate is an intermediate in the reaction
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
(3R)-linalyl diphosphate is an intermediate in the reaction
-
?
geranyl diphosphate
(-)-endo-fenchol + diphosphate
-
biosynthesis of monoterpenes
-
?
geranyl diphosphate + H2O
alpha-fenchol + diphosphate
-
products are 72% alpha-fenchol, 8.7% alpha-pinene, 14.1% limonene, 2.3% alpha-terpinolene
-
?
geranyl diphosphate + H2O
alpha-fenchol + diphosphate
-
products are 72% alpha-fenchol, 9.3% alpha-pinene, 13.8% limonene, 2.5% alpha-terpinolene
-
?
additional information
?
-
no substrate: geranylgeranyl diphosphate
-
-
?
additional information
?
-
no substrate: geranylgeranyl diphosphate
-
-
?
