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EC Number Crystallization (Commentary) Reference
Show all pathways known for 4.2.3.27Display the word mapDisplay the reaction diagram Show all sequences 4.2.3.27X-ray crystal structure of recombinant ISPS at 2.7 A resolution, and the structure of its complex with three Mg2+ and theunreactive substrate analogue dimethylallyl-S-thiolodiphosphate determined at 2.8 A resolution. Analysis suggests that the generation of isoprene from substrate dimethylallyl diphosphate occurs via a syn-periplanar elimination mechanism in which the diphosphate-leaving group serves as a general base 715917
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