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EC Number Crystallization (Commentary)
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.129in complex with FMN and dimethylallyl phosphate or FMN and dimethylallyl diphosphate
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.129in complex with substrate, to 1.4 A resolution. The active site environment is dominated by pi systems, which assist phosphate-C19 bond breakage following FMN reduction, leading to formation of the N5-C19 bond. UbiX then acts as a chaperone for adduct reorientation, via transient carbocation species, leading ultimately to formation of the dimethylallyl C39-C6 bond
Display the word mapDisplay the reaction diagram Show all sequences 2.5.1.129wild-type UbiX and mutant UbiXE49Q in complex with FMN and/or DMAP, crystal structure analysis
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