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EC Number Cofactor Commentary Reference
Show all pathways known for 4.1.1.11Display the word mapDisplay the reaction diagram Show all sequences 4.1.1.11pyruvoyl cofactor dependent on, the enzyme contains a covalently-bound pyruvoyl cofactor 728266
Show all pathways known for 4.1.1.11Display the word mapDisplay the reaction diagram Show all sequences 4.1.1.11pyruvoyl cofactor dependent on. Pathway for the formation of the pyruvoyl-dependent cofactor in ADC: the beta-hydroxyl of Ser25 attacks the carbonyl of the previous amino-acid residue (i) to form an oxyoxazolidine intermediate, which decomposes (ii) to form an ester intermediate. E1cB elimination (iii) forms a N-terminal dehydroalanyl residue which is hydrolysed (iv) to form the pyruvoyl cofactor (the alpha'-chain). The ester intermediate can also be hydrolysed to yield the inactive alpha'-chain 726592
Show all pathways known for 4.1.1.11Display the word mapDisplay the reaction diagram Show all sequences 4.1.1.11pyruvoyl cofactor the enzyme PanD is synthesized as pro-PanD, which undergoes an auto-proteolytic cleavage at residue Ser25 to yield the catalytic pyruvoyl moiety of the enzyme 728327
Show all pathways known for 4.1.1.11Display the word mapDisplay the reaction diagram Show all sequences 4.1.1.11pyruvoyl cofactor the pyruvoyl group is required for catalysis 726617
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