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EC Number	Substrates	Commentary Substrates	Organism	Products	Commentary (Products)	Reversibility
5.5.1.26	methyl nogalonate	-	Streptomyces nogalater	nogalaviketone	-	?
5.5.1.26	methyl nogalonate	the mechanism of the intramolecular aldol condensation catalysed by the enzyme is different from that of the classical aldolases, which employ covalent Schiff base formation or a metal ion cofactor. The invariant residue Asp121 acts as an acid/base catalyst during the reaction. Stabilisation of the enol(ate) intermediate is mainly achieved by the delocalisation of the electron pair over the extended p system of the substrate	Streptomyces nogalater	nogalaviketone	-	?
5.5.1.26	nogalaviketone	-	Streptomyces nogalater	methyl nogalonate	-	?

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Release 2023.1 (January 2023)