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EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
5.4.99.63
(2R)-ethylmalonyl-CoA
-
Methylorubrum extorquens
(2S)-methylsuccinyl-CoA
-
r
5.4.99.63
(2R)-ethylmalonyl-CoA
purified recombinant Ecm is unable to form methylsuccinyl-CoA from ethylmalonyl-CoA when ethylmalonyl-CoA is produced by reductive carboxylation of crotonyl-CoA carboxylase/reductase. Addition of cell extract of the gene insertion mutant ecm::kan to the enzyme assay restores ethylmalonyl-CoA mutase activity due to presence of ethylmalonyl-CoA epimerase
Cereibacter sphaeroides
(2S)-methylsuccinyl-CoA
-
?
5.4.99.63
(2R)-ethylmalonyl-CoA
a reversible enzyme
Methylorubrum extorquens
(2S)-methylsuccinyl-CoA
-
r
5.4.99.63
(2R)-ethylmalonyl-CoA
-
Methylorubrum extorquens ATCC 14718 / DSM 1338 / JCM 2805 / NCIMB 9133 / AM1
(2S)-methylsuccinyl-CoA
-
r
5.4.99.63
(2R)-ethylmalonyl-CoA
a reversible enzyme
Methylorubrum extorquens ATCC 14718 / DSM 1338 / JCM 2805 / NCIMB 9133 / AM1
(2S)-methylsuccinyl-CoA
-
r
5.4.99.63
(R)-2-methylmalonyl-CoA
0.2% of the activity with (2R)-ethylmalonyl-CoA
Cereibacter sphaeroides
succinyl-CoA
-
?
5.4.99.63
more
enzyme catalyzes the transformation of ethylmalonyl-CoA to methylsuccinyl-CoA in combination with ethylmalonyl-CoA racemase in a ethylmalonyl-CoA dependent acyl-CoA pathway for acetate assimilation
Cereibacter sphaeroides
?
-
?
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