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EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
5.1.3.18
GDP-alpha-D-mannose
-
Arabidopsis thaliana
GDP-beta-L-galactose + GDP-beta-L-gulose
-
?
5.1.3.18
GDP-alpha-D-mannose
-
Citrus sinensis
GDP-beta-L-galactose
-
?
5.1.3.18
GDP-alpha-D-mannose
GDP-D-mannose undergoes double epimerization catalyzed by GDP-D-mannose-3',5'-epimerase to form GDP-L-galactose
Citrus sinensis
GDP-beta-L-galactose
-
?
5.1.3.18
GDP-D-mannose
-
Arabidopsis thaliana
GDP-L-galactose
-
r
5.1.3.18
GDP-D-mannose
-
Solanum lycopersicum
GDP-L-galactose
-
?
5.1.3.18
GDP-D-mannose
-
Helix pomatia
GDP-L-galactose
-
?
5.1.3.18
GDP-D-mannose
r
Auxenochlorella pyrenoidosa
GDP-L-galactose
-
?
5.1.3.18
GDP-D-mannose
the reaction mixture contains at equilibrium GDP-D-mannose, GDP-L-galactose and GDP-L-gulose in a ratio of 1:0.4:0.2
Arabidopsis thaliana
GDP-L-galactose
-
r
5.1.3.18
GDP-D-mannose
the enzyme catalyzes a reversible epimerization that precedes the committed step in the biosynthesis of vitamin C, resulting in the hydrolysis of the highly energetic glycosyl-diphosphoryl linkage. The plant enzyme undergoes a complex regulation and could control the carbonflux into the vitamin C pathway in response to the redox state of thecell, stress conditions, and GDP-sugar demand for the cell wall glycoprotein biosynthesis
Arabidopsis thaliana
GDP-L-galactose
-
r
5.1.3.18
GDP-D-mannose
key enzyme in biosynthesis of vitamin C in plants
Oryza sativa
GDP-L-galactose
-
?
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