EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Trichoderma harzianum |
trichodiene + diphosphate |
- |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium graminearum |
trichodiene + diphosphate |
- |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium sporotrichioides |
trichodiene + diphosphate |
- |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium verticillioides |
trichodiene + diphosphate |
biosynthesis occurs via the (R)-bisabolyl cation to the (S)-cuprenyl cation by a 1,5-proton transfer. This conversion proceeds via a 7Si,11Re cyclisation and without exchange of the migrating proton. Side products (-)-alpha-cedrene, (+)-beta-cedrene, and (+)-alpha-funebrene found in Fusarium verticillioides can originate via the (R)-bisabolyl cation |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium verticillioides NRRL 20956 |
trichodiene + diphosphate |
biosynthesis occurs via the (R)-bisabolyl cation to the (S)-cuprenyl cation by a 1,5-proton transfer. This conversion proceeds via a 7Si,11Re cyclisation and without exchange of the migrating proton. Side products (-)-alpha-cedrene, (+)-beta-cedrene, and (+)-alpha-funebrene found in Fusarium verticillioides can originate via the (R)-bisabolyl cation |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium graminearum JCM9873 |
trichodiene + diphosphate |
- |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium sporotrichioides |
trichodiene + diphosphate + isochamigrene |
- |
? |
4.2.3.6 | (2E,6E)-farnesyl diphosphate |
- |
Fusarium sporotrichioides DSM 62425 |
trichodiene + diphosphate + isochamigrene |
- |
? |
4.2.3.6 | (3R)-nerolidyl diphosphate |
- |
Trichothecium roseum |
? |
- |
? |
4.2.3.6 | (3R)-nerolidyl diphosphate |
- |
Fusarium sporotrichioides |
? |
- |
? |