EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
  4.2.3.11 | (3R)-linalyl diphosphate + H2O |
- |
Origanum majorana |
(1S,2S,4R)-(E)-sabinene hydrate + diphosphate |
- |
? |
| 4.2.3.11 | (3R)-linalyl diphosphate + H2O |
- |
Thymus vulgaris |
(1S,2S,4R)-(E)-sabinene hydrate + diphosphate |
exclusive product of both isoforms Tps6 and Tps7 |
? |
| 4.2.3.11 | (3S)-linalyl diphosphate |
- |
Origanum majorana |
(1R,2R,4S)-(E)-sabinene hydrate + diphosphate |
- |
? |
| 4.2.3.11 | (3S)-linalyl diphosphate + H2O |
- |
Thymus vulgaris |
(1R,2R,4S)-(E)-sabinene hydrate + diphosphate |
- |
? |
| 4.2.3.11 | (3S)-linalyl diphosphate + H2O |
- |
Thymus vulgaris |
(1S,2R,4S)-(Z)-sabinene hydrate + diphosphate |
no formation of the stereoisomer (1R,2S,4R)-(Z)-sabinene hydrate |
? |
| 4.2.3.11 | 2,3-methanogeranyl diphosphate + H2O |
at 1.5% of the rate of conversion of geranyl diphosphate to sabinene hydrate, noncyclizable substrate analog of geranyl diphosphate |
Origanum majorana |
? |
- |
? |
| 4.2.3.11 | 6,7-dihydrogeranyl diphosphate + H2O |
noncyclizable substrate analog of geranyl diphosphate |
Origanum majorana |
6,7-dihydromyrcene + ? |
- |
? |
| 4.2.3.11 | geranyl diphosphate |
- |
Origanum majorana |
sabinene hydrate + diphosphate |
no free intermediate detectable in the conversion of geranyl diphosphate to sabinene hydrate |
? |
| 4.2.3.11 | geranyl diphosphate |
- |
Origanum majorana |
sabinene hydrate + diphosphate |
the configuration at c1 of geranyl diphosphate is retained in the enzymatic conversion to (+)-cis and (+)-trans-sabinene hydrate |
? |
| 4.2.3.11 | geranyl diphosphate |
- |
Origanum majorana |
sabinene hydrate + diphosphate |
constant ratio of (+)cis-sabinene hydrate to (+)-trans-sabinene hydrate is 20:1 |
? |
