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Results 1 - 10 of 19 > >>
EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 4.2.1.B8(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoic acid poor substrate Convallaria majalis ? - ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13R)-13-hydroperoxy-9,11-octadecadienoate is utilized more slowly than (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate - Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate is the preferred substrate Convallaria majalis (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retain most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the (14S)-deuterated precursor affords products that retained most of the deuterium label Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate no activity with (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate the enzyme uses preferentially 13-hydroperoxides as substrates and efficiently converts them into divinyl ether fatty acids Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. etheroleic acid ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate the S enantiomer is a much better substrate for the divinyl ether synthase compared to the R enantiomer. Incubation of (9Z,11E,13S)-[18O2]hydroperoxy-9,11-octadecadienoic acid leads to the formation of etheroleic acid which retains 18O in the ether oxygen. An intermediary role of an epoxyallylic cation in etheroleic acid biosynthesis is postulated Allium sativum (9Z,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9E,11E)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O two isomers of etheroleic acid are isolated ?
Display the reaction diagram Show all sequences 4.2.1.B8(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid - Ranunculus acris (9Z,11E)-12-[(1'Z)-hexenyloxy]-9,11-dodecadienoic acid i.e. (omega5Z)-etherolenic acid ?
Results 1 - 10 of 19 > >>