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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate - Ranunculus peltatus (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid ((11Z)-etheroleic acid) are formed in proportions 40:60, reaction with leaf homogenate ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate - Ranunculus lingua (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (11Z-etheroleic acid) are formed in proportions 40:60, reaction with leaf homogenate ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate a two-step pathway involving 13-lipoxygenase and divinyl ether synthase is responsible for biosynthesis of divinyl ethers in the plant Ranunculus lingua (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (11Z-etheroleic acid) ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate a two-step pathway involving 13-lipoxygenase and divinyl ether synthase is responsible for biosynthesis of divinyl ethers in the plant Ranunculus peltatus (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (i.e. omega5(Z)-etheroleic acid) and (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid (11Z-etheroleic acid) ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate an essentially complete loss of isotope is noted with the (14R)-deuterated precursor, whereas incubation of the 14(S)-deuterated precursor affords products that retained most of the deuterium label Ranunculus lingua (9Z,11Z)-12-[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etheroleic acid, reaction with leaf homogenate ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid i.e. 13-HPOD Selaginella moellendorffii (9Z,11E)-12[(1E)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O - ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Ranunculus lingua (9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Ranunculus peltatus (9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etherolenic acid ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Ranunculus lingua (9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etherolenic acid is the main product ?
Display the reaction diagram Show all sequences 4.2.1.B6(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate - Ranunculus peltatus (9Z,11Z)-12-[(1E,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O i.e. (11Z)-etherolenic acid is the main product ?
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