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4.2.1.174
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in contrast with previously known diterpene synthases that introduce a hydroxyl group at carbon C-8 of the labdane backbone, the MvCPS1-catalyzed reaction proceeds via oxygenation of an intermediate carbocation at C-9, yielding the bicyclic peregrinol diphosphate
Marrubium vulgare
?
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?
4.2.1.174
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reaction product analysis by GC-MS
Marrubium vulgare
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4.2.1.174
peregrinol diphosphate
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Marrubium vulgare
geranylgeranyl diphosphate + H2O
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