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Results 1 - 8 of 8
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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate key enzyme in ambiguine biosynthesis Fischerella ambigua (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate the enzyme catalyzes the biosynthesis of the isocyanide-containing antibiotic(2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate (i.e. L-tryptophan isonitrile) uncultured organism (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate the enzyme is involved in the biosynthetic pathways for vinyl isocyanides Xenorhabdus nematophila (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate i.e. L-tryptophan isonitrile, hydroxyacetone i.e. 1-hydroxypropan-2-one Xenorhabdus nematophila (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate i.e. L-tryptophan isonitrile, hydroxyacetone i.e. 1-hydroxypropan-2-one uncultured organism (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate i.e. L-tryptophan isonitrile, hydroxyacetone i.e. 1-hydroxypropan-2-one. According to the proposed mechanism, the enzyme forms an imine intermediate composed of linked L-tryptophan and D-ribulose 5-phosphate, followed by loss of the phosphate group and formation of a beta-keto imine and keto-enol tautomerization. This is followed by a C-C bond cleavage, the release of hydroxyacetone, and a retro aldol type reaction that releases formaldehyde and forms the final product Fischerella ambigua (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate key enzyme in ambiguine biosynthesis Fischerella ambigua UTEX1903 (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Display the reaction diagram Show all sequences 4.1.99.25L-tryptophan + D-ribulose 5-phosphate (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate i.e. L-tryptophan isonitrile, hydroxyacetone i.e. 1-hydroxypropan-2-one. According to the proposed mechanism, the enzyme forms an imine intermediate composed of linked L-tryptophan and D-ribulose 5-phosphate, followed by loss of the phosphate group and formation of a beta-keto imine and keto-enol tautomerization. This is followed by a C-C bond cleavage, the release of hydroxyacetone, and a retro aldol type reaction that releases formaldehyde and forms the final product Fischerella ambigua UTEX1903 (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + hydroxyacetone + formaldehyde + phosphate + H2O - ?
Results 1 - 8 of 8
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