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EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
2.3.1.165
acetoacetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Penicillium griseofulvum
6-methyl triacetic acid lactone + CoA + NADP+
-
?
2.3.1.165
acetoacetyl-CoA + malonyl-CoA
5% of the rate of 6-methylsalicylic acid synthesis
Penicillium griseofulvum
6-methyl triacetic acid lactone + CoA
-
?
2.3.1.165
acetoacetyl-CoA + malonyl-CoA + NADPH
-
Penicillium griseofulvum
?
-
?
2.3.1.165
acetoacetyl-CoA + malonyl-CoA + NADPH
-
Penicillium griseofulvum NRRL 2159A
?
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Aspergillus terreus
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Aspergillus aculeatus
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Penicillium griseofulvum
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Aspergillus niger
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
-
Streptomyces antibioticus
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
2.3.1.165
acetyl-CoA + 3 malonyl-CoA + NADPH + H+
ATX by itself can synthesize tetraketide and release 6-methylsalicylate as the free acid without involvement of serine protease-type thioesterase, the product 6-methylsalicylate is retained on the acyl-carrier-protein until its release from ATX, product-releasing mechanism, overview
Aspergillus terreus
6-methylsalicylate + 4 CoA + 3 CO2 + NADP+ + H2O
-
?
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