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Results 1 - 10 of 18 > >>
EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B11,2,3-trinitroglycerol + 2 NADPH + 2 H+ - Pseudomonas putida ? - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrophenol + 2 NADPH + 2 H+ - Pseudomonas putida ? - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas sp. N-hydroxy-2-methyl-3,5-dinitroaniline + 2 NADP+ + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas putida N-hydroxy-2-methyl-3,5-dinitroaniline + 2 NADP+ + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas putida N-hydroxy-2-methyl-3,5-dinitroaniline + 2 NADP+ + H2O i.e. 2-hydroxylamino-2,6-dinitrotoluene. The amount of N-hydroxy-2-methyl-3,5-dinitroaniline is larger than the amount of N-hydroxy-4-methyl-3,5-dinitroaniline formed. In a further nonenzymatic reaction nitrite is released and N-(2-methyl-3,5-dinitrophenyl)-N-4-methyl-3,5-dinitrophenyl-hydroxylamine and eventually N-(2-methyl-3,5-dinitrophenyl)-N-4-methyl-3,5-dinitroaniline are produced. In addition the aromatic ring of 2,4,6-trinitrotoluene is susceptibe to nucleophilic attack by hydride ions to form Meisenheimer complex intermediates (monohydride and dihydride complexes) which also form secondary diaryl hydroxylamines and secondary diarylamine with release of nitrite ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas putida KT 2240 N-hydroxy-2-methyl-3,5-dinitroaniline + 2 NADP+ + H2O i.e. 2-hydroxylamino-2,6-dinitrotoluene. The amount of N-hydroxy-2-methyl-3,5-dinitroaniline is larger than the amount of N-hydroxy-4-methyl-3,5-dinitroaniline formed. In a further nonenzymatic reaction nitrite is released and N-(2-methyl-3,5-dinitrophenyl)-N-4-methyl-3,5-dinitrophenyl-hydroxylamine and eventually N-(2-methyl-3,5-dinitrophenyl)-N-4-methyl-3,5-dinitroaniline are produced. In addition the aromatic ring of 2,4,6-trinitrotoluene is susceptibe to nucleophilic attack by hydride ions to form Meisenheimer complex intermediates (monohydride and dihydride complexes) which also form secondary diaryl hydroxylamines and secondary diarylamine with release of nitrite ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas putida N-hydroxy-4-methyl-3,5-dinitroaniline + 2 NADP+ + H2O i.e. 4-hydroxylamino-2,6-dinitrotoluene. The amount of N-hydroxy-4-methyl-3,5-dinitroaniline is larger than the amount of N-hydroxy-2-methyl-3,5-dinitroaniline formed. In a further nonenzymatic reaction nitrite is released and N,N-bis-(3,5-dinitrotolyl)-hydroxylamine and eventually N,N-bis-(3,5-dinitrotolyl)-amine are produced. In addition the aromatic ring of 2,4,6-trinitrotoluene is susceptible to nucleophilic attack by hydride ions to form Meisenheimer complex intermediates (monohydride and dihydride complexes) which also form the secondary diaryl hydroxylamines and the secondary diarylamine with release of nitrite ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B12,4,6-trinitrotoluene + 2 NADPH + 2 H+ - Pseudomonas putida KT 2240 N-hydroxy-4-methyl-3,5-dinitroaniline + 2 NADP+ + H2O i.e. 4-hydroxylamino-2,6-dinitrotoluene. The amount of N-hydroxy-4-methyl-3,5-dinitroaniline is larger than the amount of N-hydroxy-2-methyl-3,5-dinitroaniline formed. In a further nonenzymatic reaction nitrite is released and N,N-bis-(3,5-dinitrotolyl)-hydroxylamine and eventually N,N-bis-(3,5-dinitrotolyl)-amine are produced. In addition the aromatic ring of 2,4,6-trinitrotoluene is susceptible to nucleophilic attack by hydride ions to form Meisenheimer complex intermediates (monohydride and dihydride complexes) which also form the secondary diaryl hydroxylamines and the secondary diarylamine with release of nitrite ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B1CB1954 + NADPH + H+ - Pseudomonas putida ? + hydroxylamine + NADP+ - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.7.1.B1cyclohexenone + NADPH + H+ - Pseudomonas putida ? - ?
Results 1 - 10 of 18 > >>