EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.20.11 | (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + O2 |
- |
Fischerella ambigua |
3-[(Z)-2-isocyanoethenyl]-1H-indole + succinate + 2 CO2 + H2O |
- |
? |
1.14.20.11 | (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + O2 |
- |
Fischerella ambigua UTEX 1903 |
3-[(Z)-2-isocyanoethenyl]-1H-indole + succinate + 2 CO2 + H2O |
- |
? |
1.14.20.11 | more |
enzyme initiates stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C=C bond installation |
Fischerella ambigua |
? |
- |
? |
1.14.20.11 | more |
enzyme initiates stereoselective olefination via a benzylic C-H bond activation by an Fe(IV)-oxo intermediate, and the reaction likely proceeds through a radical- or carbocation-induced decarboxylation to complete C=C bond installation |
Fischerella ambigua UTEX 1903 |
? |
- |
? |