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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the reaction diagram Show all sequences 1.14.19.8more no activity with substrate analogue 6,7-dihydropentalenolactone, because the C1 carbocation is not anchimerically stabilized by the 6,7-double bond of pentalenolactone F. Enzyme-ligand interaction via three residues, F232, M77, and M81 that are unique to PntM and its orthologues and absent from essentially all other P450s Streptomyces arenae ? - ?
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ - Streptomyces exfoliatus pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ir
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ - Streptomyces avermitilis pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ir
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ - Streptomyces arenae pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ir
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ apparent ability of PntM to catalyze an exclusive carbocation-based oxidative rearrangement Streptomyces arenae pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ?
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ - Streptomyces exfoliatus UC5319 pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ir
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + 2 reduced ferredoxin + 2 H+ - Streptomyces arenae TUE469 pentalenolactone + 2 oxidized ferredoxin + 2 H2O - ir
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + NADPH + H+ - Streptomyces exfoliatus pentalenolactone + NADP+ + H2O - ?
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + NADPH + H+ - Streptomyces arenae pentalenolactone + NADP+ + H2O - ?
Display the reaction diagram Show all sequences 1.14.19.8pentalenolactone F + O2 + NADPH + H+ - Streptomyces exfoliatus UC5319 pentalenolactone + NADP+ + H2O - ?
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