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EC Number Substrates Commentary Substrates Organism Products Commentary (Products) Reversibility
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(2S,3R)-2-aminoicosane-1,3-diol + reduced acceptor + O2 - Helianthus annuus (E)-(2S,3R)-2-aminoicos-8-ene-1,3-diol + (Z)-(2S,3R)-2-aminoicos-8-ene-1,3-diol + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(E)-sphing-4-enine + reduced acceptor + O2 - Candida albicans (2S,3R,4E,8E)-2-aminooctadeca-4,8-diene-1,3-diol + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(E)-sphing-4-enine + reduced acceptor + O2 - Candida albicans TUA6 (2S,3R,4E,8E)-2-aminooctadeca-4,8-diene-1,3-diol + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(R)-9-fluorophytosphinganine + reduced acceptor + O2 exclusively produces (Z)-9-fluoro-8-phytosphingenine. This result is explained by an initial attack onto the C8-HR and syn-elimination of two vicinal hydrogen atoms via an anti-conformation of the substrate. An initial attack on the C9-F is excluded and generates no product Helianthus annuus (Z)-9-fluoro-8-phytosphingenine + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(S)-8-fluorophytosphinganine + reduced acceptor + O2 product predominantly transformed to (Z)-8-fluoro-8-phytosphingenine along with only trace amounts of the (E)-8-fluoro-8-phytosphingenine (ratio 95:5). This ratio indicates that the fluorinated substrate strongly favors the anti-configuration at the active center of the desaturase Helianthus annuus (Z)-8-fluoro-8-phytosphingenine + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.4(S)-9-fluorophytosphinganine + reduced acceptor + O2 produces (E)-9-fluoro-8-phytosphingenine as the sole reaction product. Only the initial attack on the C9-HR in combination with the gauche-conformation of the substrate is productive Helianthus annuus (E)-9-fluoro-8-phytosphingenine + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.411,14,17-eicosatrienoic acid + reduced acceptor + O2 - Euglena gracilis 8,11,14,17-eicosatetraenoic acid + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.411,14,17-eicosatrienoic acid + reduced acceptor + O2 20:3n-3, yield 20:4n-3 Papio anubis ? - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.411,14-eicosadienoic acid + reduced acceptor + O2 - Euglena gracilis 8,11,14-eicosatrienoic acid + acceptor + H2O - ?
Display the word mapDisplay the reaction diagram Show all sequences 1.14.19.411,14-eicosadienoic acid + reduced acceptor + O2 20:2n-6, yield 20:3n-6 Papio anubis ? - ?
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