EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.14.141 | (+)-marmesin + NADP + H+ + O2 |
- |
Petroselinum crispum |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + H2O |
- |
r |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Petroselinum crispum |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Ammi majus |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Apium graveolens |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Pastinaca sativa |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
the enzyme is the first committed monooxygenase of linear furanocoumarin biosynthesis, pathway overview |
Ammi majus |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
the substrate is synthesized from demethylsuberosin by the marmesin synthase, biosynthesis of furanocoumarin phytoalexin which are then excreted from the endoplasmic reticulum lumen into the cell culture medium |
Ammi majus |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
release of acetone by syn-elimination |
Ammi majus |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
very poor activity with (-)-marmesin, i.e. nodakenetin |
Petroselinum crispum |
psoralen + [oxidized NADPH-hemoprotein reductase] + acetone + 2 H2O |
- |
? |
1.14.14.141 | (+)-marmesin + [reduced NADPH-hemoprotein reductase] + O2 |
- |
Cullen corylifolium |
psoralen + acetone + [oxidized NADPH-hemoprotein reductase] + H2O |
- |
? |