EC Number   |
Substrates |
Organism |
Products |
Reversibility |
|---|
  1.14.11.43 | (R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH. SdpA activity is completely absent in the absence of 2-oxoglutarate |
Sphingobium herbicidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-mecoprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH. SdpA activity is completely absent in the absence of 2-oxoglutarate |
Sphingobium herbicidovorans |
2-methyl-4-chlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop |
Delftia acidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
the enzyme catalyzes the initial step of microbial degradation of the chiral herbicide (R,S)-2-(2,4-dichlorophenoxy)propionate (R,S-dichlorprop) |
Sphingobium herbicidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop |
Sphingobium herbicidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop. RdpA exclusively transforms the (S)-enantiomer of dichlorprop |
Sphingobium herbicidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop. SdpA is specific for the (S) enantiomer |
Sphingobium herbicidovorans |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop |
Delftia acidovorans MC1 |
2,4-dichlorophenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-mecoprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). SdpA is highly specific for the cleavage of the S-configuration of dichlorprop and mecoprop |
Delftia acidovorans |
4-chloro-2-methylphenol + pyruvate + succinate + CO2 |
- |
? |
| 1.14.11.43 | (S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 |
i.e. (S)-mecoprop. RdpA exclusively transforms the (S)-enantiomer of mecoprop |
Sphingobium herbicidovorans |
4-chloro-2-methylphenol + pyruvate + succinate + CO2 |
- |
? |
