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Results 1 - 5 of 5
EC Number
Substrates
Commentary Substrates
Organism
Products
Commentary (Products)
Reversibility
more
enzyme may undergo isomerization or a ring-opening reaction via a Delta3,Delta2-enoyl-CoA isomerase-like mechanism
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more
enzyme may undergo isomerization or a ring-opening reaction via a Delta3,Delta2-enoyl-CoA isomerase-like mechanism
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2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA
enzyme acts as a ring 1,2-epoxyphenylacetyl-CoA isomerase forming oxepin-CoA. It mediates the formation and stabilization of the enolate form by abstracting a proton from the side chain at C2 of ring 1,2-epoxyphenylacetyl-CoA. Addition of the abstracted proton to C8, which becomes C4, of the ring leads to a rearrangement of the double bonds and results in a C-C cleavage of the two epoxy-C-O bonds, yielding the oxepin
2-oxepin-2(3H)-ylideneacetyl-CoA
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?
2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA
enzyme acts as a ring 1,2-epoxyphenylacetyl-CoA isomerase forming oxepin-CoA. It mediates the formation and stabilization of the enolate form by abstracting a proton from the side chain at C2 of ring 1,2-epoxyphenylacetyl-CoA. Addition of the abstracted proton to C8, which becomes C4, of the ring leads to a rearrangement of the double bonds and results in a C-C cleavage of the two epoxy-C-O bonds, yielding the oxepin
2-oxepin-2(3H)-ylideneacetyl-CoA
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?
2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA
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2-oxepin-2(3H)-ylideneacetyl-CoA
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r
Results 1 - 5 of 5