EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.13.22 | (+)-camphor + NADPH + O2 |
- |
Nocardia globerula |
? |
- |
? |
1.14.13.22 | (+)-camphor + NADPH + O2 |
- |
Acinetobacter sp. |
? |
- |
? |
1.14.13.22 | (+)-dihydrocarvone + NADPH + O2 |
- |
Nocardia globerula |
? |
- |
? |
1.14.13.22 | (+)-dihydrocarvone + NADPH + O2 |
- |
Acinetobacter sp. |
? |
- |
? |
1.14.13.22 | (1aS,4aS,8aS)-8a-methylhexahydronaphthalene-1,6-dione + NADPH + O2 |
WielandMiescher ketone, no activity with the (1aR,4aR,8aR)-stereoisomer, stereoselective formation of the cis-(5aR,9aS)-isomer |
Acinetobacter calcoaceticus |
(5aR,9aS)-9a-methylhexahydrobenzo[b]oxepine-2,7-dione + NADP+ + H2O |
- |
? |
1.14.13.22 | (1aS,4aS,8aS)-8a-methylhexahydronaphthalene-1,6-dione + NADPH + O2 |
WielandMiescher ketone, no activity with the (1aR,4aR,8aR)-stereoisomer, stereoselective formation of the cis-(5aR,9aS)-isomer |
Acinetobacter calcoaceticus NCIMB 9871 |
(5aR,9aS)-9a-methylhexahydrobenzo[b]oxepine-2,7-dione + NADP+ + H2O |
- |
? |
1.14.13.22 | (1R)-bicyclo[2.2.1]heptane-2,5-dione + NADPH + O2 |
74.4% of the activity with cyclohexanone |
Ilyonectria destructans |
? + NADP+ + H2O |
- |
? |
1.14.13.22 | (2R)-2-ethylcyclohexanone + NADPH + H+ + O2 |
92% conversion, 30% enantiomeric excess, (-)-product |
Polaromonas sp. |
(7S)-7-ethyloxepan-2-one + NADP+ + H2O |
- |
? |
1.14.13.22 | (2R,6S)-2,6-dimethylcyclohexanone + NADPH + H+ + O2 |
- |
Rhodococcus sp. HI-31 |
cis-3, 7-dimethyl-2-oxepanone + NADP+ + H2O |
- |
? |
1.14.13.22 | (2R,6S)-2,6-dimethylcyclohexanone + NADPH + O2 + H+ |
- |
Acinetobacter calcoaceticus |
(3R,7S)-3,7-dimethyloxepan-2-one + NADP+ + H2O |
90% conversion at 20 h, 99% enantiomeric excess |
? |