EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
1.14.13.22 | 4a-methyltetrahydro-1aH-naphtho[1,8a-b]oxirene-2,5(3H,6H)-dione + NADPH + O2 |
- |
Acinetobacter calcoaceticus |
(1R,3S,7S)-7-methyl-2,8-dioxatricyclo[5.5.0.01,3]dodecane-4,9-dione + NADP+ + H2O |
enantiopure product |
? |
1.14.13.22 | 4a-methyltetrahydro-1aH-naphtho[1,8a-b]oxirene-2,5(3H,6H)-dione + NADPH + O2 |
- |
Acinetobacter calcoaceticus NCIMB 9871 |
(1R,3S,7S)-7-methyl-2,8-dioxatricyclo[5.5.0.01,3]dodecane-4,9-dione + NADP+ + H2O |
enantiopure product |
? |
1.14.13.22 | bicyclo[3.2.0]hept-2-en-6-one + NADPH + H+ + O2 |
- |
Acinetobacter calcoaceticus |
(1R,5S)-3-oxabicyclo-[3.3.0]oct-6-en-3-one + (1S,5R)-2-oxabicyclo-[3.3.0]oct-6-en-3-one + NADP+ + H2O |
- |
? |
1.14.13.22 | bicyclo[3.2.0]hept-2-en-6-one + NADPH + H+ + O2 |
- |
Acinetobacter calcoaceticus NCIMB 9871 |
(1R,5S)-3-oxabicyclo-[3.3.0]oct-6-en-3-one + (1S,5R)-2-oxabicyclo-[3.3.0]oct-6-en-3-one + NADP+ + H2O |
- |
? |
1.14.13.22 | (2R,6S)-2,6-dimethylcyclohexanone + NADPH + O2 + H+ |
- |
Acinetobacter calcoaceticus |
(3R,7S)-3,7-dimethyloxepan-2-one + NADP+ + H2O |
90% conversion at 20 h, 99% enantiomeric excess |
? |
1.14.13.22 | (2R,6S)-2,6-dimethylcyclohexanone + NADPH + O2 + H+ |
- |
Acinetobacter calcoaceticus NCIMB 9871 |
(3R,7S)-3,7-dimethyloxepan-2-one + NADP+ + H2O |
90% conversion at 20 h, 99% enantiomeric excess |
? |
1.14.13.22 | 3-methylcyclohexanone + NADPH + O2 + H+ |
- |
Acinetobacter calcoaceticus |
(4S)-4-methyloxepan-2-one + (6R)-6-methyloxepan-2-one + NADP+ + H2O |
- |
? |
1.14.13.22 | (4aR,8aS)-8a-methylhexahydronaphthalene-1,6(2H,5H)-dione + NADPH + O2 |
- |
Acinetobacter calcoaceticus |
(5aR,9aS)-9a-methylhexahydrobenzo[b]oxepine-2,7-dione + (4aS,6S,8aR)-6-hydroxy-8a-methyloctahydronaphthalen-1-one + NADP+ + H2O |
- |
? |
1.14.13.22 | (4aR,8aS)-8a-methylhexahydronaphthalene-1,6(2H,5H)-dione + NADPH + O2 |
- |
Acinetobacter calcoaceticus NCIMB 9871 |
(5aR,9aS)-9a-methylhexahydrobenzo[b]oxepine-2,7-dione + (4aS,6S,8aR)-6-hydroxy-8a-methyloctahydronaphthalen-1-one + NADP+ + H2O |
- |
? |
1.14.13.22 | (1aS,4aS,8aS)-8a-methylhexahydronaphthalene-1,6-dione + NADPH + O2 |
WielandMiescher ketone, no activity with the (1aR,4aR,8aR)-stereoisomer, stereoselective formation of the cis-(5aR,9aS)-isomer |
Acinetobacter calcoaceticus |
(5aR,9aS)-9a-methylhexahydrobenzo[b]oxepine-2,7-dione + NADP+ + H2O |
- |
? |