  3.3.2.14 | more |
evaluation of the C and N isotope fractionation associated with abiotic and biological 2,4-dinitroanisole (DNAN) hydrolysis through alkaline hydrolysis at high pH as well as enzymatic hydrolysis by Nocardioides sp. JS1661 and partially purified DNAN O-demethylase for decontamination of DNAN. Whereas both reactions generate 2,4-dinitrophenol (DNP), compound-specific isotope analysis (CSIA) of DNAN and DNP reveal that these reactions occur by different mechanisms, thus different mechanisms of alkaline and enzymatic hydrolysis of the insensitive munition component 2,4-dinitroanisole lead to identical products |
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