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EC Number General Information Commentary Reference
Display the reaction diagram Show all sequences 2.6.1.B17physiological function enzyme is part of the chloroeremomycin biosynthetic cluster. Non-heme iron dioxygenase HmaS catalyzes the synthesis of L-4-hydroxymandelate from 4-hydroxyphenylpyruvate. The L-4-hydroxymandelate is subsequently converted to L-4-hydroxyphenylglycine via L-4-hydroxymandelate oxidase Hmo catalyzed conversion of L-4-hydroxymandelate to L-4-hydroxybenzoylformate followed by 4-hydroxyphenylglycine transaminase HpgT catalyzed transamination of 4-hydroxybenzoylformate to 4-hydroxyphenylglycine. The biosynthesis of L-4-hydroxyphenylglycine is proposed to be a catalytic cycle initiated by the production of 4-hydroxyphenylpyruvate 724727
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