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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 5.5.1.26nogalaviketone = methyl nogalonate the mechanism of the intramolecular aldol condensation catalysed by the enzyme is different from that of the classical aldolases, which employ covalent Schiff base formation or a metal ion cofactor. The invariant residue Asp121 acts as an acid/base catalyst during the reaction. Stabilisation of the enol(ate) intermediate is mainly achieved by the delocalisation of the electron pair over the extended p system of the substrate 729639
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