EC Number   |
Reaction |
Reference |
|---|
   5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
formation of an unusual oxygen-sensitive Co(II) species during catalysis |
3529 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
mechanism |
2986, 3453, 3526 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
mechanism via protein-bound free radicals |
3528 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
rotation of the exo-methylene group of 2-methyleneglutarate |
3524 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
the enzyme catalyzes the reversible migration of an acryloyl residue from the alpha-carbon to the beta-carbon of propionate with inversion of configuration at the alpha-carbon |
2988 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
the steric course of the reaction is such that the acrylyl residue migrates from the beta-carbon to the alpha-carbon of the propionate with inversion of configuration at the alpha-carbon |
3526 |
| 5.4.99.4 | 2-Methyleneglutarate = 2-methylene-3-methylsuccinate |
unimolecular free radical rearrangement via 3-butenyl and cyclopropylmethyl intermediates is a reasonable mechanism for the rearrangement step of the enzyme |
3526 |
