EC Number |
Reaction |
Reference |
---|
5.3.99.4 | (5Z,13E,15S)-9alpha,11alpha-epidioxy-15-hydroxyprosta-5,13-dienoate = (5Z,13E,15S)-6,9alpha-epoxy-11alpha,15-dihydroxyprosta-5,13-dienoate |
mechanism |
3200, 37474, 37475 |
5.3.99.4 | (5Z,13E,15S)-9alpha,11alpha-epidioxy-15-hydroxyprosta-5,13-dienoate = (5Z,13E,15S)-6,9alpha-epoxy-11alpha,15-dihydroxyprosta-5,13-dienoate |
prostaglandin endoperoxyde PGH2 prostacyclin PGI2 , a mechanism with the participation of a heme-thiolate protein is proposed |
37463 |
5.3.99.4 | (5Z,13E,15S)-9alpha,11alpha-epidioxy-15-hydroxyprosta-5,13-dienoate = (5Z,13E,15S)-6,9alpha-epoxy-11alpha,15-dihydroxyprosta-5,13-dienoate |
radical-mediated isomerizytion with high product fidelity |
680910 |