EC Number |
Reaction |
Reference |
---|
5.2.1.8 | peptidylproline (omega=180) = peptidylproline (omega=0) |
covalent mechanism which involves an approximately tetravalent carbon of the prolyl imidic bond for the transition state of reaction |
2512 |
5.2.1.8 | peptidylproline (omega=180) = peptidylproline (omega=0) |
mechanism that involves distortion of bound substrate with a twisted, 90° , peptidyl-propyl amide bond |
2539 |
5.2.1.8 | peptidylproline (omega=180) = peptidylproline (omega=0) |
simple twisted amide transition state catalytic mechanism, modeling, overview. The serine carbonyl does not rehybridize from sp2 to sp3 in the rate-determining step, ruling out a nucleophilic addition mechanism |
727034 |
5.2.1.8 | peptidylproline (omega=180) = peptidylproline (omega=0) |
the refolding mechanism is similar in the presence and absence of the enzyme |
-, 2513 |