EC Number   |
Reaction |
Reference |
|---|
    4.2.3.24 | (2E,6E)-farnesyl diphosphate = amorpha-4,11-diene + diphosphate |
- |
- |
| 4.2.3.24 | (2E,6E)-farnesyl diphosphate = amorpha-4,11-diene + diphosphate |
enzyme first catalyzes a 1,6 ring closure with a subsequent 1,10 closure |
663753 |
| 4.2.3.24 | (2E,6E)-farnesyl diphosphate = amorpha-4,11-diene + diphosphate |
mechanism includes a bisabolyl carbocation and 1,3-hydride shift, detailed analysis |
666108 |
| 4.2.3.24 | (2E,6E)-farnesyl diphosphate = amorpha-4,11-diene + diphosphate |
mechanism involves isomerzation of farnesyl diphosphate to (R)-nerolidyl diphosphate, ionization, and C-1,C-6-ring closure to generate a bisabolyl cation, followed by a 1,3-hydride shift, 1,10-ring closure, and deprotonation at either C-12 or C-13 |
663779 |
