EC Number |
Reaction |
Reference |
---|
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
- |
- |
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
cyclization mechanism catalyzed by KSs and the Ile mutants, via ent-pimar-15-en-8-yl, ent-beyeran-16-yl, and ent-kauran-16-yl intermediates, detailed overview |
747870 |
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
cyclization mechanism derived from quantum chemical calculation for the formation of ent-kaurene and related diterpenes, overview |
748876 |
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
reaction mechanism, overview |
-, 749301 |
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
the determination of the final products of CPS/KSs in bryophytes depends on the sequence and structure of the C-terminal regions of CPS/KSs. Thus, the type A cyclization reaction of both PpCPS/KS and JsCPS /KS occurs near the C-terminal region of the polypeptides |
714971 |
4.2.3.19 | ent-copalyl diphosphate = ent-kaurene + diphosphate |
the hydrophobicity and size of the side chain residue at the bifunctional CPS/KS amino acid 710 is responsible for quenching the ent-kauranyl cation by the addition of a water molecule. The determination of the final products of CPS/KSs in bryophytes depends on the sequence and structure of the C-terminal regions of CPS/KSs. Thus, the type A cyclization reaction of both PpCPS/KS and JsCPS /KS occurs near the C-terminal region of the polypeptides |
714971 |