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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 4.2.1.121(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O - -
Display the word mapDisplay the reaction diagram Show all sequences 4.2.1.121(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O intervention of an epoxycarbonium ion intermediate. A mechanism is proposed 704806
Display the word mapDisplay the reaction diagram Show all sequences 4.2.1.121(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O selective removal of the pro-R hydrogen at C-8 in the biosynthesis of colneleic acid -, 703621, 704808
Display the word mapDisplay the reaction diagram Show all sequences 4.2.1.121(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O the oxygen inserted enzymically between carbons 9- and 10- of the C-18 chain in forming colneleic acid originates from 18O2 gas via the hydroperoxide group of linoleic acid. A mechanism is proposed 704805
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