EC Number |
Reaction |
Reference |
---|
4.1.1.5 | (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 |
- |
- |
4.1.1.5 | (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 |
(R)-3-hydroxybutan-2-one i.e. ((R)-2-acetoin) |
- |
4.1.1.5 | (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 |
catalytic decarboxylation mechanism, overview |
726550 |
4.1.1.5 | (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 |
mechanism |
649197 |
4.1.1.5 | (2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 |
the carboxy group of alpha-acetolactate is replaced regiospecifically by hydrogen. This process takes place with overall inversion of configuration |
4644 |