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EC Number	Reaction	Commentary	Reference
4.1.1.45	2-amino-3-(3-oxoprop-1-en-1-yl)but-2-enedioate = 2-aminomuconate semialdehyde + CO2	-	-
4.1.1.45	2-amino-3-(3-oxoprop-1-en-1-yl)but-2-enedioate = 2-aminomuconate semialdehyde + CO2	the decarboxylation occurs first to generate an unstable alpha-aminomuconate-epsilon-semialdehyde intermediate, which then undergoes a relatively slow release from the enzyme and a much slower cyclization to yield the final product	680375

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Release 2023.1 (January 2023)