EC Number   |
Reaction |
Reference |
|---|
   3.7.1.18 | bornane-2,6-dione + H2O = [(1S)-4-hydroxy-2,2,3-trimethylcyclopent-3-enyl]acetate |
- |
- |
| 3.7.1.18 | bornane-2,6-dione + H2O = [(1S)-4-hydroxy-2,2,3-trimethylcyclopent-3-enyl]acetate |
analysis of the molecular determinants of both mechanism and enantiotopic selectivity in reactions catalysed by OCH and reaction mechanism, putative Asp154-His145 dyad, overview |
-, 718527 |
| 3.7.1.18 | bornane-2,6-dione + H2O = [(1S)-4-hydroxy-2,2,3-trimethylcyclopent-3-enyl]acetate |
involvement of five residues, His45, His122, His145, Asp154, and Glu244, in catalysis, catalytic His145/Asp154 dyad. The the pendant acetate of the product (2S,4S)-alpha-campholinic acid hydrogen bonded to a His145/Asp154 dyad and the endocyclic carbonyl of the cyclopentane ring hydrogen bonds to Trp40, prochiral selectivity, base-catalyzed mechanism of C-C bond cleavage, overview |
-, 719819 |
| 3.7.1.18 | bornane-2,6-dione + H2O = [(1S)-4-hydroxy-2,2,3-trimethylcyclopent-3-enyl]acetate |
mechanism of carbon-carbon bond cleavage by 6-oxo camphor hydrolase |
719814 |
