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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 1.8.1.52-mercaptoethanesulfonate + acetoacetate + NADP+ = 2-(2-oxopropylthio)ethanesulfonate + CO2 + NADPH + H+ - -
Display the word mapDisplay the reaction diagram Show all sequences 1.8.1.52-mercaptoethanesulfonate + acetoacetate + NADP+ = 2-(2-oxopropylthio)ethanesulfonate + CO2 + NADPH + H+ detailed reaction mechanism in a catalytic cycle, active site structure 657919
Display the word mapDisplay the reaction diagram Show all sequences 1.8.1.52-mercaptoethanesulfonate + acetoacetate + NADP+ = 2-(2-oxopropylthio)ethanesulfonate + CO2 + NADPH + H+ reaction mechanism for 2-KPCC begins with formation of enzyme-substrate disulfide adduct by the reduced form of the redox active disulfide. This step is followed by release of enolacetone anion intermediates for 2-KPCC. The primary catalytic fate of the enolacetone intermediate for the wild-type (Phe501) or variant (His501) 2-KPCC is acetoacetate or acetone, respectively 742523
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