EC Number |
Reaction |
Reference |
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1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
a selenium-containing protein, selenoprotein, is essential component of the enzyme |
636465, 636466 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
cleavage mechanism for the pyruvoyl group dependent reductase starting from cysteine |
-, 484935, 636462 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
Cys 359 of GrdD is the thiol responsible for the formation of the acetyl thioester during catalysis of arsenate-dependent hydrolysis of acetyl phosphate |
636473 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
glycine pathway is used for acetate synthesis |
-, 636475 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
GrdD of protein component C catalyses the arsenate-dependent decomposition of acetyl phosphate, whereas GrdC completely inactive |
636473 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
mechanism |
-, 484935, 636462, 636464 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
mechanism, thiols are present in protein C that is acetylated during reaction |
636476 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
the 48000 Da subunit of protein component C catalyses the arsenate-dependent decomposition of actetyl phosphate, a possible role of the 57000 Da subunit of protein component C could be the involvement in the reductive dehydration which leads to the cleavage of the protein A-bound carboxymethyl-selenoether to ketene and oxidized protein A |
636472 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
the protein C component catalyses the arsenate-dependent decomposition of acetyl phosphate |
636467, 636469, 636472 |
1.21.4.2 | acetyl phosphate + NH3 + thioredoxin disulfide + H2O = glycine + phosphate + thioredoxin |
the protein component C serves as the acetyl group acceptor in the overall reaction |
636467 |