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EC Number Reaction Commentary Reference
Display the word mapDisplay the reaction diagram Show all sequences 1.2.3.1an aldehyde + H2O + O2 = a carboxylate + H2O2 - -
Display the word mapDisplay the reaction diagram Show all sequences 1.2.3.1an aldehyde + H2O + O2 = a carboxylate + H2O2 base catalyzed mechanism. Residue E1265 acts as an active site base that abstracts a proton from the Mo-OH group, which in turn undertakes a nucleophilic attack on the substrate benzaldehyde. After hydride transfer to the Mo= S group, the initial intermediate breaks down, with the transient formation of a paramagnetic MoV species, followed by displacement of product by a water molecule to return to the starting LMoVIOS(OH) state. The roles of residues Met884 and Val806 are stabilization of substrate binding 700901
Display the word mapDisplay the reaction diagram Show all sequences 1.2.3.1an aldehyde + H2O + O2 = a carboxylate + H2O2 concerted mechanism 699722
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