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Results 1 - 4 of 4
EC Number Reaction Commentary Reference
Display the reaction diagram Show all sequences 1.13.11.722-hydroxyethylphosphonate + O2 = hydroxymethylphosphonate + formate - -
Display the reaction diagram Show all sequences 1.13.11.722-hydroxyethylphosphonate + O2 = hydroxymethylphosphonate + formate catalytic mechanism -, 745162
Display the reaction diagram Show all sequences 1.13.11.722-hydroxyethylphosphonate + O2 = hydroxymethylphosphonate + formate initial substrate oxidation by a ferric-superoxo-intermediate and a second oxidation by a ferryl species, catalytic mechanism, detailed overview -, 745390
Display the reaction diagram Show all sequences 1.13.11.722-hydroxyethylphosphonate + O2 = hydroxymethylphosphonate + formate the reaction proceeds via a transient iron(IV)-oxo (ferryl) complex, a mechanism that involves activation of an O-H bond by the ferryl complex is proposed. The isotope-sensitive C-H-cleavage step is not primarily rate-limiting for the overall catalytic cycle. The reaction does exhibit a significant 2H-kinetic isotope effect on kcat/Km for O2, which implies reversible formation of the C-H-cleaving intermediate -, 745178
Results 1 - 4 of 4