EC Number |
Reaction |
Reference |
---|
3.3.2.9 | 1-(4-methoxyphenyl)-N-methyl-N-[(3-methyloxetan-3-yl)methyl]methanamine + H2O = 2-({[(4-methoxyphenyl)methyl](methyl)amino}methyl)-2-methylpropane-1,3-diol |
(2) |
- |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
(1) |
- |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
reaction mechanism, catalytic triad |
654503 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
two step mechanism with formation of of a hydroxyl-alkyl-enzyme intermediate, catalytic triad |
660713 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
two step mechanism with formation of of a hydroxyl-alkyl-enzyme intermediate, the catalytic triad is Asp226-His431-Glu404 with polarizing residues Tyr299 and Tyr374 |
660713 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
the catalytic triad is Asp226-His431-Asp352, catalytic mechanism involving an ester intermediate formed by alkylation of an active site carboxyl group |
661476 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
formation of threo-1,2-diphenyl-1,2-ethanediols from all epoxides involving anti-stereospecific opening of the oxirane ring with about 90% preference for the (S)-carbon to give nearly optically pure (R,R)-diols |
661494 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
the catalytic triad is Asp223-Glu402-His429, the active site includes an oxyanion hole |
662669 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
active site structure, quantitative structure-activity relationships, molecular modelling |
663432 |
3.3.2.9 | cis-stilbene oxide + H2O = (1R,2R)-1,2-diphenylethane-1,2-diol |
ring-opening reaction mechanism, overview |
755352 |