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Results 1 - 8 of 8
EC Number
Reaction
Commentary
Reference
formate + NAD+ = CO2 + NADH
ordered bi-bi mechanism, NAD+ is the first substrate and NADH is the last product
formate + NAD+ = CO2 + NADH
ordered kinetic mechanism with NAD+ adding before formate
formate + NAD+ = CO2 + NADH
sequential mechanism
formate + NAD+ = CO2 + NADH
sequential ordered bi-bi mechanism
formate + NAD+ = CO2 + NADH
ordered mechanism
formate + NAD+ = CO2 + NADH
hydride-transfer step is rate-limiting
formate + NAD+ = CO2 + NADH
ordered BiBi mechanism with NAD+ and NADH being the first substrate and the second product, resp.
formate + NAD+ = CO2 + NADH
reaction mechanism: step I, formate binds directly to Mo, displacing Se-Cys140. Step II, the alpha-proton from formate may be transferred to the nearby His141 that acts as general base. Alternatively, step II may involve a selenium-carboxylated intermediate. Step III, electrons from MoIV are transferred via the 4Fe-4S center to an external electron acceptor and the catalytic cycle is completed
Results 1 - 8 of 8