EC Number   |
Natural Substrates |
|---|
   4.2.1.92 | (13S)-hydroperoxy-(9Z,11E)-octadecadienoic acid |
- |
| 4.2.1.92 | (8R)-hydroperoxyeicosatetraenoic acid |
the substrate is converted to an unstable allene oxide product via the FeIV-OH intermediate, Compound II, the native enzyme shows a strong preference for its natural substrate |
| 4.2.1.92 | (8R)-hydroperoxylinoleic acid + H2O |
- |
| 4.2.1.92 | (9R)-hydroperoxy-(10E,12Z,15Z)-octadecatrienoic acid |
- |
| 4.2.1.92 | (9R,10E,12Z)-9-hydroperoxy-10,12-octadecadienoic acid |
- |
| 4.2.1.92 | (9S)-hydroperoxy-(10E,12Z)-octadecadienoic acid |
recombinant FOXB_01332 oxidizes 18:2n-6 to (9S)-hydroperoxy-(10E,12Z)-octadecadienoic acid by hydrogen abstraction and antarafacial insertion of molecular oxygen and sequentially to an allene oxide, (9S,10)-epoxy-(10Z,12Z)-octadecadienoic acid, which gives nonenzymatic hydrolysis products alpha- and gamma-ketols |
| 4.2.1.92 | (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoic acid |
- |
| 4.2.1.92 | (9S,10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoic acid |
- |
| 4.2.1.92 | (9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoic acid |
- |
| 4.2.1.92 | (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoic acid |
- |
