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EC Number
Natural Substrates
Commentary (Nat. Sub.)
1.13.11.79
FMNH2 + NADH + H+ + O2
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1.13.11.79
FMNH2 + NADH + H+ + O2 + alloxan
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1.13.11.79
FMNH2 + O2
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1.13.11.79
FMNH2 + O2
FMNH2 reacts with oxygen to yield flavin hydroperoxide, which then undergoes a ring expansion with loss of a water molecule to produce intermediate A. This disintegrates further as a result of four hydrolysis reactions in which it is attacked by water molecules. The resulting diaminobenzene product undergoes two oxidation reactions, to form 5,6-dimethylbenzimidazole
1.13.11.79
FMNH2 + O2
the rate of formation of the intermediate product unprotonated C4a-peroxyflavin is influenced by substitutions at C8 of FMN
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