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EC Number Metals/Ions Commentary Reference
Show all pathways known for 1.14.20.3Display the word mapDisplay the reaction diagram Show all sequences 1.14.20.3Fe2+ Fe(II)-dependent oxygenase. An Fe(IV)-oxo intermediate abstracts the hydrogen (H*) from C5, and tyrosine 165, a residue not visualized in the published structures of CarC lacking bound substrate, donates H* to the opposite face of the resultant radical. The reaction oxidizes the Fe(II) cofactor to Fe(III), limiting wild-type CarC to one turnover, but substitution of the H-donating tyrosine disables stereoinversion and confers to CarC the capacity for catalytic substrate oxidation 746493
Show all pathways known for 1.14.20.3Display the word mapDisplay the reaction diagram Show all sequences 1.14.20.3Fe2+ iron(II) oxygenase 743903
Show all pathways known for 1.14.20.3Display the word mapDisplay the reaction diagram Show all sequences 1.14.20.3Fe2+ required for activity 722055
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